2) Metal Based Inks for Printed /Flexible Electronics

Most of the recent studies on conductive nanoinks have focused on silver nanoparticles because of their high conductivity and oxidation resistance. However, silver metals are too expensive to be used in large quantities. Furthermore, silver electrical circuits often suffer the problem of electro-migration. Therefore, Cu NPs are considered an alternative for conductive nanoinks because of their high conductivity, low cost, and reduced electro-migration effect. The major issue with Cu-based inks is easy oxidation in ambient air; the presence of copper oxide raises the sintering temperature and dramatically increases the electrical resistivity. To overcome these limitations, various types of copper-based inks have been developed to allow low-temperature (<150 °C) sintering for the preparation of conductive Cu films on flexible substrates: (i) reduction-assisted particle-based inks, (ii) nanoparticle-based inks with specific ligands, (iii) precursor-type inks (e.g., inks based on metal−organic decomposition, MOD), and (iv) combination inks. Our group focuses on low-temperature sintering of Cu-based inks to produce conductive Cu films on flexible polymer/paper substrates, ensuring the durability of sintered Cu films to safeguard their environmental stability and mechanical flexibility. These performances have become the most important task from a practical standpoint.

 

銅ペースト/大気下・低温焼成 

<Copper based conductive inks>
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<Liquid metals>
・Manyuan et al. J. Colloid Interface Sci.649,581(2023)
・Otsuki et al. Mater. Chem. Phys.314, 128844(2024)