Abstract<\/p>\n\n\n\n
Synthesis and Characterization of N,N-Dimethylformamide-Protected Palladium Nanoparticles and Their Use in the Suzuki\u2013Miyaura Cross-Coupling Reaction<\/a> <\/p>\n\n\n\n Abstract: <\/strong>Herein, the synthesis of new N,N-dimethylformamide (DMF)-protected palladium nanoparticles (Pd NPs-OAc) employing Pd (OAc)2 (\u2550 Pd(OCOCH3)2) as the NP precursor is reported. Pd NPs-OAc were comprehensively characterized by transmission electron microscopy, FT-IR, NMR, and X-ray photoelectron spectroscopy to determine the Pd NP size distribution and the coordination state of DMF. Pd NPs-OAc were compared with Pd NPs-Cl, using PdCl2 as the NP precursor. The Suzuki\u2013Miyaura cross-coupling reaction proceeded efficiently in the presence of Pd NPs-OAc and a high catalytic activity was observed with a turnover number of up to 1.5 \u00d7 105. Furthermore, the Pd NP-OAc catalysts could be recycled at least five times.<\/p>\n","protected":false},"excerpt":{"rendered":" Abstract Synthesis and Characterization of N,N-Dimethylformamide-Protected Palladium Nanoparticles and Their Use in the Suzuki\u2013Miyaura Cross-Coupling Reaction J. Ishida, M. Nakatsuji, T.Nagata, H. Kaw Read More …<\/a><\/p>\n","protected":false},"author":61,"featured_media":0,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"_monsterinsights_skip_tracking":false,"_monsterinsights_sitenote_active":false,"_monsterinsights_sitenote_note":"","_monsterinsights_sitenote_category":0,"footnotes":""},"categories":[18],"tags":[],"class_list":["post-2038","post","type-post","status-publish","format-standard","hentry","category-recent-publications"],"_links":{"self":[{"href":"https:\/\/wps.itc.kansai-u.ac.jp\/colloid\/wp-json\/wp\/v2\/posts\/2038","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/wps.itc.kansai-u.ac.jp\/colloid\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/wps.itc.kansai-u.ac.jp\/colloid\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/wps.itc.kansai-u.ac.jp\/colloid\/wp-json\/wp\/v2\/users\/61"}],"replies":[{"embeddable":true,"href":"https:\/\/wps.itc.kansai-u.ac.jp\/colloid\/wp-json\/wp\/v2\/comments?post=2038"}],"version-history":[{"count":1,"href":"https:\/\/wps.itc.kansai-u.ac.jp\/colloid\/wp-json\/wp\/v2\/posts\/2038\/revisions"}],"predecessor-version":[{"id":2039,"href":"https:\/\/wps.itc.kansai-u.ac.jp\/colloid\/wp-json\/wp\/v2\/posts\/2038\/revisions\/2039"}],"wp:attachment":[{"href":"https:\/\/wps.itc.kansai-u.ac.jp\/colloid\/wp-json\/wp\/v2\/media?parent=2038"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/wps.itc.kansai-u.ac.jp\/colloid\/wp-json\/wp\/v2\/categories?post=2038"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/wps.itc.kansai-u.ac.jp\/colloid\/wp-json\/wp\/v2\/tags?post=2038"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}
J. Ishida, M. Nakatsuji, T.Nagata, H. Kawasaki, T.Suzuki, Y. Obora*,
ACS Omega, 2<\/em>020, https:\/\/doi.org\/10.1021\/acsomega.0c01006<\/p>\n\n\n\n