{"id":49,"date":"2020-08-02T02:45:51","date_gmt":"2020-08-01T17:45:51","guid":{"rendered":"http:\/\/wps.itc.kansai-u.ac.jp\/cmr\/?page_id=49"},"modified":"2020-08-07T11:32:04","modified_gmt":"2020-08-07T02:32:04","slug":"background","status":"publish","type":"page","link":"https:\/\/wps.itc.kansai-u.ac.jp\/cmr\/background\/","title":{"rendered":"\u7814\u7a76\u80cc\u666f"},"content":{"rendered":"\n<p class=\"has-normal-font-size\">1.\n\u306f\u3058\u3081\u306b<\/p>\n\n\n\n<p>\u3000\u751f\u547d\u6d3b\u52d5\u306b\u304a\u3051\u308b\u5316\u5b66\u53cd\u5fdc\u306e\u591a\u304f\u306b\u306f\u9175\u7d20\u304c\u95a2\u4e0e\u3057\u3066\u304a\u308a\uff0c\u7279\u5b9a\u306e\u7269\u8cea(\u57fa\u8cea)\u3092\u89e6\u5a92\u7684\u306b\u5909\u63db\u3057\u3066\u3044\u308b\u3002\u3053\u306e\u9175\u7d20\u53cd\u5fdc\u3092\u52b9\u7387\u3088\u304f\u884c\u3046\u306b\u306f\uff0c\u591a\u304f\u306e\u7269\u8cea\u306e\u4e2d\u304b\u3089\u5fc5\u8981\u3068\u3055\u308c\u308b\u57fa\u8cea\u3092\u9078\u5225\u3059\u308b\u5fc5\u8981\u304c\u3042\u308a\uff0c\u5206\u5b50\u306e\u5f62\u3092\u7279\u5b9a\u3057\u3066\u53cd\u5fdc\u306b\u5fc5\u8981\u306a\u57fa\u8cea\u304b\u5224\u5225\u3057\u3066\u3044\u308b\u3002\u3053\u306e\u306f\u305f\u3089\u304d\u3092\u5206\u5b50\u8a8d\u8b58\u3068\u3044\u3044\uff0c\u3055\u307e\u3056\u307e\u306a\u5206\u5b50\u9593\u306b\u306f\u305f\u3089\u304f\u529b(\u5206\u5b50\u9593\u76f8\u4e92\u4f5c\u7528)\u3092\u7528\u3044\u3066\uff0c\u5fc5\u8981\u306a\u5206\u5b50\u3092\u9078\u5225\u3057\u3066\u3044\u308b\u3002\u5206\u5b50\u9593\u76f8\u4e92\u4f5c\u7528\u306f\u751f\u547d\u6d3b\u52d5\u306b\u304a\u3044\u3066\u3060\u3051\u3067\u306f\u306a\u304f\uff0c\u5316\u5b66\u53cd\u5fdc\u306e\u7cbe\u5bc6\u6027\u3092\u9ad8\u3081\u305f\u308a\uff0c\u3044\u308f\u3086\u308b\u300c\u5206\u5b50\u30de\u30b7\u30f3\u300d\u306e\u99c6\u52d5\u529b\u3068\u3057\u3066\u5229\u7528\u3055\u308c\u305f\u308a\u3057\u3066\u304a\u308a<sup>1)<\/sup>\uff0c\u3053\u308c\u304b\u3089\u307e\u3059\u307e\u3059\u305d\u306e\u91cd\u8981\u6027\u304c\u5897\u3059\u3082\u306e\u3068\u8003\u3048\u3089\u308c\u308b\u3002<\/p>\n\n\n\n<p>2.\n\u5206\u5b50\u9593\u76f8\u4e92\u4f5c\u7528\u3000\uff0d\u975e\u5171\u6709\u7d50\u5408\u6027\u76f8\u4e92\u4f5c\u7528\uff0d<\/p>\n\n\n\n<p>\u5206\u5b50\u9593\u76f8\u4e92\u4f5c\u7528\u306b\u306f\uff0c\u9759\u96fb\u7684\u76f8\u4e92\u4f5c\u7528\uff0c\u6c34\u7d20\u7d50\u5408\uff0c\u82b3\u9999\u74b0\u76f8\u4e92\u4f5c\u7528\uff0c\u30d5\u30a1\u30f3\u30c7\u30eb\u30ef\u30fc\u30eb\u30b9\u529b\u306a\u3069\u304c\u3042\u308a(\u56f3 1)<sup>2)<\/sup>\uff0c\u3053\u308c\u3089\u306f\u5206\u5b50\u3092\u5f62\u6210\u3059\u308b\u529b\uff1d\u5171\u6709\u7d50\u5408\u3068\u5bfe\u6bd4\u3057\u3066\u300c\u975e\u5171\u6709\u7d50\u5408\u6027\u76f8\u4e92\u4f5c\u7528\u300d\u3068\u547c\u3070\u308c\u308b\u3002\u3053\u308c\u3089\u975e\u5171\u6709\u7d50\u5408\u6027\u76f8\u4e92\u4f5c\u7528\u306e\u500b\u3005\u306e\u5b89\u5b9a\u5316\u30a8\u30cd\u30eb\u30ae\u30fc\u306f\u5171\u6709\u7d50\u5408\u306b\u6bd4\u3079\u3066\u5c0f\u3055\u3044\u304c\uff0c\u5206\u5b50\u8a8d\u8b58\u5834\u3067\u306f\u8907\u6570\u306e\u975e\u5171\u6709\u7d50\u5408\u6027\u76f8\u4e92\u4f5c\u7528\u304c\u5354\u594f\u7684\u306b\u306f\u305f\u3089\u304f\u3053\u3068\u3067\uff0c\u5927\u304d\u306a\u5b89\u5b9a\u5316\u30a8\u30cd\u30eb\u30ae\u30fc\u3092\u9054\u6210\u3059\u308b\u3068\u3068\u3082\u306b\uff0c\u5171\u6709\u7d50\u5408\u306b\u6bd4\u3079\u3066\u5c0f\u3055\u306a\u30a8\u30cd\u30eb\u30ae\u30fc\u3067\u5206\u5b50\u9593\u306e\u76f8\u4e92\u4f5c\u7528\u3092\u5236\u5fa1\u3057\u3066\u3044\u308b\u3002\u6eb6\u5a92\u306b\u5bfe\u3059\u308b\u89aa\u548c\u6027\u3084\uff0c\u76f8\u4e92\u4f5c\u7528\u306e\u65b9\u5411\u6027\u306a\u3069\u304c\u7570\u306a\u308b\u591a\u69d8\u306a\u975e\u5171\u6709\u7d50\u5408\u6027\u76f8\u4e92\u4f5c\u7528\u304c\u3042\u308b\u304c\uff0c\u3053\u3053\u3067\u306f\u6c34\u7d20\u7d50\u5408\u3068\u82b3\u9999\u74b0\u304c\u95a2\u4e0e\u3059\u308b\u76f8\u4e92\u4f5c\u7528\u306b\u3064\u3044\u3066\u53d6\u308a\u4e0a\u3052\u308b\u3002<\/p>\n\n\n\n<figure class=\"wp-block-image size-large\"><img loading=\"lazy\" decoding=\"async\" width=\"545\" height=\"516\" src=\"https:\/\/wps.itc.kansai-u.ac.jp\/cmr\/wp-content\/uploads\/sites\/189\/2020\/08\/\u30b9\u30e9\u30a4\u30c91-1.jpg\" alt=\"\" class=\"wp-image-62\" srcset=\"https:\/\/wps.itc.kansai-u.ac.jp\/cmr\/wp-content\/uploads\/sites\/189\/2020\/08\/\u30b9\u30e9\u30a4\u30c91-1.jpg 545w, https:\/\/wps.itc.kansai-u.ac.jp\/cmr\/wp-content\/uploads\/sites\/189\/2020\/08\/\u30b9\u30e9\u30a4\u30c91-1-300x284.jpg 300w\" sizes=\"auto, (max-width: 545px) 100vw, 545px\" \/><\/figure>\n\n\n\n<p>\u3000\u6c34\u7d20\u7d50\u5408\u306f\uff0c1) \u76f8\u4e92\u4f5c\u7528\u306e\u5b89\u5b9a\u5316\u30a8\u30cd\u30eb\u30ae\u30fc\u304c\u6bd4\u8f03\u7684\u5927\u304d\u3044 2) \u76f8\u4e92\u4f5c\u7528\u306b\u65b9\u5411\u6027\u304c\u3042\u308b\u306a\u3069\u304b\u3089\uff0c\u751f\u4f53\u4e2d\u306b\u304a\u3051\u308b\u5206\u5b50\u8a8d\u8b58\u3084\u9175\u7d20\u53cd\u5fdc\u306e\u8abf\u6574\u90e8\u4f4d\u3068\u3057\u3066\u3088\u304f\u7528\u3044\u3089\u308c\u3066\u3044\u308b\u3002\u307e\u305f\uff0c\u76f8\u4e92\u4f5c\u7528\u57fa\u304c\u751f\u7406\u7684 pH\u306b\u8fd1\u3044\u9178\u89e3\u96e2\u5b9a\u6570(p<em>K<\/em>a)\u3092\u793a\u3059\u3082\u306e\u304c\u591a\u304f\u3042\u308a\uff0c\u76f8\u4e92\u4f5c\u7528\u8fd1\u508d\u306e pH\u3092\u5909\u5316\u3055\u305b\u308b\u3053\u3068\u306b\u3088\u308b\u6c34\u7d20\u7d50\u5408\u306e\u751f\u6210\u30fb\u89e3\u6d88\u304c\u53ef\u80fd\u3067\u3042\u308b\u3053\u3068\u3082\uff0c\u751f\u4f53\u5185\u3067\u306e\u5206\u5b50\u8a8d\u8b58\u306b\u7528\u3044\u3089\u308c\u308b\u4e00\u56e0\u3068\u8003\u3048\u3089\u308c\u308b\u3002\u751f\u4f53\u5206\u5b50\u306e\u591a\u304f\u306f C, H, N, O, S\u539f\u5b50\u306a\u3069\u304b\u3089\u69cb\u6210\u3055\u308c\u308b\u6709\u6a5f\u5206\u5b50\u3067\u3042\u308a\uff0c\u30a2\u30df\u30ce\u57fa\uff0c\u30b0\u30a2\u30cb\u30b8\u30ce\u57fa\uff0c\u30d2\u30c9\u30ed\u30ad\u30b7\u57fa\uff0c\u30ab\u30eb\u30dc\u30cb\u30eb\u57fa\uff0c\u30ab\u30eb\u30dc\u30ad\u30b7\u57fa\uff0c\u30c1\u30aa\u30fc\u30eb\u57fa\u306a\u3069\u304c\u6c34\u7d20\u7d50\u5408\u306e\u76f8\u4e92\u4f5c\u7528\u57fa\u3068\u3057\u3066\u77e5\u3089\u308c\u3066\u3044\u308b(\u56f3 2)\u3002\u306a\u304b\u3067\u3082\uff0c\u30a2\u30df\u30f3\u57fa\u3084\u30b0\u30a2\u30cb\u30b8\u30ce\u57fa\u304c\u30d7\u30ed\u30c8\u30f3\u5316\u3057\u305f\u30a2\u30f3\u30e2\u30cb\u30a6\u30e0\u3042\u308b\u3044\u306f\u30b0\u30a2\u30cb\u30b8\u30cb\u30a6\u30e0\u90e8\u4f4d\u3068\uff0c\u30ab\u30eb\u30dc\u30ad\u30b7\u57fa\u304c\u8131\u30d7\u30ed\u30c8\u30f3\u5316\u3057\u305f\u30ab\u30eb\u30dc\u30ad\u30b7\u30ec\u30fc\u30c8\u90e8\u4f4d\u306e\u9593\u306e\u76f8\u4e92\u4f5c\u7528\u306f\uff0c\u30a2\u30f3\u30e2\u30cb\u30a6\u30e0\uff0c\u30b0\u30a2\u30cb\u30b8\u30cb\u30a6\u30e0\u306b\u3042\u308b\u6b63\u96fb\u8377\u3068\u30ab\u30eb\u30dc\u30ad\u30b7\u30ec\u30fc\u30c8\u306e\u8ca0\u96fb\u8377\u9593\u306b\u306f\u305f\u3089\u304f\u9759\u96fb\u7684\u76f8\u4e92\u4f5c\u7528\u3068\uff0cN\uff0dH\u7d50\u5408\u3068\u30ab\u30eb\u30dc\u30ad\u30b7\u30ec\u30fc\u30c8\u306e\u9178\u7d20\u539f\u5b50\u9593\u306b\u306f\u305f\u3089\u304f\u6c34\u7d20\u7d50\u5408\u304c\u540c\u6642\u306b\u306f\u305f\u3089\u304d\uff0c\u9759\u96fb\u7684\u76f8\u4e92\u4f5c\u7528\u306b\u3088\u308b\u5927\u304d\u306a\u5206\u5b50\u9593\u76f8\u4e92\u4f5c\u7528\u306e\u5b89\u5b9a\u6027\u3068\uff0c\u6c34\u7d20\u7d50\u5408\u306b\u3088\u308b\u65b9\u5411\u9078\u629e\u6027\u304c\u5f97\u3089\u308c\u308b\u3053\u3068\u304b\u3089\uff0c\u591a\u304f\u306e\u5206\u5b50\u8a8d\u8b58\u5834\u306b\u898b\u53d7\u3051\u3089\u308c\u308b(\u4f8b\u3048\u3070\u56f3 1\u306e\u56f2\u307f)\u3002<\/p>\n\n\n\n<figure class=\"wp-block-image size-large\"><img loading=\"lazy\" decoding=\"async\" width=\"590\" height=\"418\" src=\"https:\/\/wps.itc.kansai-u.ac.jp\/cmr\/wp-content\/uploads\/sites\/189\/2020\/08\/\u30b9\u30e9\u30a4\u30c92-1.jpg\" alt=\"\" class=\"wp-image-63\" srcset=\"https:\/\/wps.itc.kansai-u.ac.jp\/cmr\/wp-content\/uploads\/sites\/189\/2020\/08\/\u30b9\u30e9\u30a4\u30c92-1.jpg 590w, https:\/\/wps.itc.kansai-u.ac.jp\/cmr\/wp-content\/uploads\/sites\/189\/2020\/08\/\u30b9\u30e9\u30a4\u30c92-1-300x213.jpg 300w\" sizes=\"auto, (max-width: 590px) 100vw, 590px\" \/><\/figure>\n\n\n\n<p>\u3000\u4e00\u65b9\uff0c\u82b3\u9999\u74b0\u304c\u95a2\u4e0e\u3059\u308b\u76f8\u4e92\u4f5c\u7528\u3082\u3044\u304f\u3064\u304b\u306e\u5206\u5b50\u8a8d\u8b58\u5834\u306b\u304a\u3044\u3066\u305d\u306e\u5f79\u5272\u3092\u679c\u305f\u3057\u3066\u304a\u308a<sup>3)<\/sup>\uff0c\u82b3\u9999\u74b0\u3092\u6709\u3059\u308b\u7269\u8cea\u3092\u8b58\u5225\u3059\u308b\u306e\u306b\u529b\u3092\u767a\u63ee\u3059\u308b\u3068\u8003\u3048\u3089\u308c\u308b\u304c\uff0c\u305d\u306e\u4ed6\u306e\u975e\u5171\u6709\u7d50\u5408\u6027\u76f8\u4e92\u4f5c\u7528\u306b\u6bd4\u3079\u308b\u3068\u305d\u306e\u4f5c\u7528\u539f\u7406\u306f\u305d\u308c\u307b\u3069\u7814\u7a76\u3055\u308c\u3066\u306f\u3044\u306a\u3044\u3002<\/p>\n\n\n\n<p>3.\n\u30ad\u30e9\u30ea\u30c6\u30a3\u3068\u5149\u5b66\u5206\u5272<\/p>\n\n\n\n<p>\u3000\u30ad\u30e9\u30ea\u30c6\u30a3\u3092\u6709\u3059\u308b\u5206\u5b50\u306b\u306f\uff0c\u305d\u306e\u7acb\u4f53\u7570\u6027\u4f53\u3068\u3057\u3066\u30a8\u30ca\u30f3\u30c1\u30aa\u30de\u30fc\u304c\u3042\u308a(\u56f3 3)\uff0c\u3053\u308c\u3089\u4e8c\u3064\u306e\u7570\u6027\u4f53\u5206\u5b50\u306f\uff0c\u504f\u5149\u306b\u5bfe\u3059\u308b\u6027\u8cea\u3092\u9664\u3044\u3066\u7269\u7406\u7684\u5316\u5b66\u7684\u6027\u8cea\u304c\u540c\u3058\u3067\u3042\u308b\u3053\u3068\u304b\u3089\u533a\u5225\u3059\u308b\u3053\u3068\u304c\u96e3\u3057\u3044\u3002\u3057\u304b\u3057\uff0c\u3053\u308c\u3089\u306e\u7570\u6027\u4f53\u9593\u3067\u306f\u751f\u4f53\u306b\u5bfe\u3059\u308b\u4f5c\u7528\u304c\u7570\u306a\u308b\u3053\u3068\u304c\u77e5\u3089\u308c\u3066\u304a\u308a\uff0c\u4f8b\u3048\u3070\u4e00\u65b9\u306e\u7570\u6027\u4f53\u304c\u85ac\u306a\u3069\u306e\u3088\u3046\u306b\u4f53\u306b\u6709\u7528\u306b\u7528\u3044\u3089\u308c\u308b\u3053\u3068\u304c\u3042\u308b\u306e\u306b\u5bfe\u3057\u3066\uff0c\u4ed6\u65b9\u306e\u7570\u6027\u4f53\u306f\u6bd2\u6027\u3092\u793a\u3059\u3068\u3044\u3063\u305f\u7269\u8cea\u3082\u3042\u308b\u3002\u3057\u305f\u304c\u3063\u3066\uff0c\u85ac\u306a\u3069\u306e\u751f\u4f53\u306b\u7528\u3044\u308b\u3082\u306e\u306e\u539f\u6599\u3068\u3059\u308b\u5834\u5408\uff0c\u5fc5\u8981\u306a\u4e00\u65b9\u306e\u7570\u6027\u4f53\u3092\u7d14\u5ea6\u826f\u304f\u5f97\u308b\u5fc5\u8981\u304c\u3042\u308b\u3002\u4e00\u822c\u306b\uff0c\u30ad\u30e9\u30ea\u30c6\u30a3\u3092\u8003\u616e\u305b\u305a\u306b\u30a2\u30df\u30ce\u9178\u3084\u7cd6\u306a\u3069\u3068\u3044\u3063\u305f\u30ad\u30e9\u30ea\u30c6\u30a3\u3092\u6709\u3059\u308b\u5316\u5408\u7269\u3092\u5408\u6210\u3057\u305f\u5834\u5408\u306f\uff0c\u30a8\u30ca\u30f3\u30c1\u30aa\u30de\u30fc\u3069\u3046\u3057\u304c\u5f53\u91cf\u6df7\u3056\u3063\u305f\u30e9\u30bb\u30df\u4f53\u304c\u5f97\u3089\u308c\u308b\u3002\u30e9\u30bb\u30df\u4f53\u304b\u3089\u4e00\u65b9\u306e\u5149\u5b66\u7570\u6027\u4f53\u306e\u307f\u3092\u53d6\u308a\u51fa\u3059\u65b9\u6cd5\u306f\u300c\u5149\u5b66\u5206\u5272\u300d\u3068\u8a00\u308f\u308c\uff0c\u5fc5\u8981\u306a\u5149\u5b66\u6d3b\u6027\u4f53\u3092\u5f97\u308b\u65b9\u6cd5\u3068\u3057\u3066\u3088\u304f\u7528\u3044\u3089\u308c\u308b\u3002<\/p>\n\n\n\n<figure class=\"wp-block-image size-large\"><img loading=\"lazy\" decoding=\"async\" width=\"455\" height=\"310\" src=\"https:\/\/wps.itc.kansai-u.ac.jp\/cmr\/wp-content\/uploads\/sites\/189\/2020\/08\/\u30b9\u30e9\u30a4\u30c93-1.jpg\" alt=\"\" class=\"wp-image-64\" srcset=\"https:\/\/wps.itc.kansai-u.ac.jp\/cmr\/wp-content\/uploads\/sites\/189\/2020\/08\/\u30b9\u30e9\u30a4\u30c93-1.jpg 455w, https:\/\/wps.itc.kansai-u.ac.jp\/cmr\/wp-content\/uploads\/sites\/189\/2020\/08\/\u30b9\u30e9\u30a4\u30c93-1-300x204.jpg 300w\" sizes=\"auto, (max-width: 455px) 100vw, 455px\" \/><\/figure>\n\n\n\n<p>\u3000\u5149\u5b66\u5206\u5272\u5264\u3092\u7528\u3044\u308b\u65b9\u6cd5\u306f\u5149\u5b66\u5206\u5272\u3067\u3082\u3063\u3068\u3082\u3088\u304f\u7528\u3044\u3089\u308c\u308b\u3002\u3053\u308c\u306f\u5149\u5b66\u7570\u6027\u4f53\u306e\u6df7\u5408\u7269\u3067\u3042\u308b\u30e9\u30bb\u30df\u4f53\u306e\u9178(\u3042\u308b\u3044\u306f\u5869\u57fa)\u306b\uff0c\u30ad\u30e9\u30ea\u30c6\u30a3\u304c\u6c7a\u307e\u3063\u3066\u3044\u308b\u5869\u57fa(\u3042\u308b\u3044\u306f\u9178)\u3092\u4f5c\u7528\u3055\u305b\u3066\u9178\u5869\u57fa\u53cd\u5fdc\u3092\u7528\u3044\u3066\u30b8\u30a2\u30b9\u30ec\u30c6\u30aa\u30de\u30fc\u5869\u3078\u3068\u8a98\u5c0e\u3057\uff0c\u30b8\u30a2\u30b9\u30c6\u30ec\u30aa\u30de\u30fc\u9593\u306e\u6027\u8cea\u306e\u9055\u3044(\u7279\u306b\u6eb6\u89e3\u5ea6\u306e\u9055\u3044)\u3092\u7528\u3044\u3066\u5206\u96e2\u3092\u884c\u3046\u65b9\u6cd5\u3067\u3042\u308b(\u56f3 4)\u3002\u4e00\u822c\u7684\u306b\uff0c\u30b8\u30a2\u30b9\u30c6\u30ec\u30aa\u30de\u30fc\u5869\u306e\u3046\u3061\u6eb6\u89e3\u6027\u304c\u5c0f\u3055\u3044\u96e3\u6eb6\u6027\u5869\u306e\u65b9\u304c\u5149\u5b66\u7d14\u5ea6\u306f\u9ad8\u304f\u306a\u308b\u306e\u3067\uff0c\u53cd\u5fdc\u6db2\u4e2d\u306b\u751f\u3058\u308b\u7d50\u6676\u3092\u308d\u904e\u306b\u3088\u3063\u3066\u96c6\u3081\uff0c\u5fc5\u8981\u3067\u3042\u308c\u3070\u518d\u7d50\u6676\u3092\u884c\u3044\uff0c\u305d\u3053\u304b\u3089\u9ad8\u7d14\u5ea6\u306e\u5149\u5b66\u6d3b\u6027\u4f53\u3092\u5f97\u308b\u3053\u3068\u304c\u53ef\u80fd\u3067\u3042\u308b\u3002<\/p>\n\n\n\n<figure class=\"wp-block-image size-large\"><img loading=\"lazy\" decoding=\"async\" width=\"692\" height=\"442\" src=\"https:\/\/wps.itc.kansai-u.ac.jp\/cmr\/wp-content\/uploads\/sites\/189\/2020\/08\/\u30b9\u30e9\u30a4\u30c94-1.jpg\" alt=\"\" class=\"wp-image-65\" srcset=\"https:\/\/wps.itc.kansai-u.ac.jp\/cmr\/wp-content\/uploads\/sites\/189\/2020\/08\/\u30b9\u30e9\u30a4\u30c94-1.jpg 692w, https:\/\/wps.itc.kansai-u.ac.jp\/cmr\/wp-content\/uploads\/sites\/189\/2020\/08\/\u30b9\u30e9\u30a4\u30c94-1-300x192.jpg 300w\" sizes=\"auto, (max-width: 692px) 100vw, 692px\" \/><\/figure>\n\n\n\n<p>\u3000\u3053\u3053\u3067\uff0c\u4e8c\u3064\u306e\u30b8\u30a2\u30b9\u30c6\u30ec\u30aa\u30de\u30fc\u5869(\u96e3\u6eb6\u6027\u5869\u3068\u6613\u6eb6\u6027\u5869)\u306b\u3064\u3044\u3066\u8003\u3048\u3066\u307f\u308b\u3002\u30b8\u30a2\u30b9\u30c6\u30ec\u30aa\u30de\u30fc\u5869\u306f\uff0c\u5869\u57fa\u6027\u7269\u8cea\u304c\u30d7\u30ed\u30c8\u30f3\u5316\u3057\u305f\u967d\u30a4\u30aa\u30f3\u3068\u9178\u6027\u7269\u8cea\u304c\u8131\u30d7\u30ed\u30c8\u30f3\u5316\u3057\u305f\u9670\u30a4\u30aa\u30f3\u304b\u3089\u69cb\u6210\u3055\u308c\u3066\u304a\u308a\uff0c\u30a4\u30aa\u30f3\u9593\u306e\u9759\u96fb\u7684\u306a\u5f15\u529b\u304c\u5869\u3092\u5f62\u6210\u3059\u308b\u5927\u304d\u306a\u529b\u3068\u306a\u3063\u3066\u3044\u308b\u3002\u3057\u305f\u304c\u3063\u3066\u5869\u306e\u6eb6\u89e3\u6027\u306f\u3053\u306e\u30a4\u30aa\u30f3\u9593\u306e\u529b\u306b\u5927\u304d\u304f\u5f71\u97ff\u3092\u53d7\u3051\uff0c\u96e3\u6eb6\u6027\u5869\u3067\u306f\u6613\u6eb6\u6027\u5869\u3088\u308a\u3082\u30a4\u30aa\u30f3\u9593\u306e\u5f15\u529b\u304c\u5f37\u3044\u305f\u3081\u306b\u6eb6\u5a92\u306b\u6eb6\u3051\u3060\u3057\u306b\u304f\u304f\u306a\u3063\u3066\u3044\u308b\u3068\u8003\u3048\u3089\u308c\u308b\u3002\u3057\u304b\u3057\u4e8c\u3064\u306e\u30b8\u30a2\u30b9\u30c6\u30ec\u30aa\u30de\u30fc\u5869\u3067\u306f\uff0c\u5869\u3092\u69cb\u6210\u3057\u3066\u3044\u308b\u5404\u30a4\u30aa\u30f3\u306f\u7acb\u4f53\u914d\u7f6e\u4ee5\u5916\u540c\u3058\u3067\u3042\u308a\uff0c\u30a4\u30aa\u30f3\u9593\u306b\u306f\u305f\u3089\u304f\u9759\u96fb\u7684\u306a\u529b\u306b\u306f\u305d\u308c\u307b\u3069\u5927\u304d\u306a\u9055\u3044\u304c\u3042\u308b\u3068\u306f\u601d\u308f\u308c\u306a\u3044\u3002<\/p>\n\n\n\n<p>4.\n\u7acb\u4f53\u9078\u629e\u306b\u304a\u3051\u308b\u6c34\u7d20\u7d50\u5408\u306e\u91cd\u8981\u6027<\/p>\n\n\n\n<p>\u3000\u9178\u5869\u57fa\u53cd\u5fdc\u3092\u7528\u3044\u305f\u5149\u5b66\u5206\u5272\u306b\u7528\u3044\u3089\u308c\u308b\u5869\u57fa\u6027\u5149\u5b66\u5206\u5272\u5264\uff0c\u3042\u308b\u3044\u306f\u5149\u5b66\u5206\u5272\u306b\u4f9b\u3059\u308b\u5869\u57fa\u6027\u7269\u8cea\u306f\uff0c\u30b8\u30a2\u30b9\u30c6\u30ec\u30aa\u30de\u30fc\u5869\u3068\u3057\u305f\u3068\u304d\u306b\u30d7\u30ed\u30c8\u30f3\u5316\u3055\u308c\u967d\u30a4\u30aa\u30f3\u3068\u306a\u308b\u5fc5\u8981\u304c\u3042\u308b\u305f\u3081\uff0c\u305d\u306e\u591a\u304f\u306f\u30d7\u30ed\u30c8\u30f3\u5316\u3092\u53d7\u3051\u3084\u3059\u3044\u30a2\u30df\u30f3\u985e\u3067\u3042\u308b\u3053\u3068\u304c\u591a\u3044\u3002\u30a2\u30df\u30f3\u985e\u304c\u30d7\u30ed\u30c8\u30f3\u5316\u3059\u308b\u3053\u3068\u306b\u3088\u308b\u751f\u6210\u3059\u308b\u6709\u6a5f\u30a2\u30f3\u30e2\u30cb\u30a6\u30e0\u30a4\u30aa\u30f3\u306f\uff0c\u7a92\u7d20\u539f\u5b50\u306b 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NH<sub>3<\/sub>\u304c\u6790\u51fa\u3057\uff0c\u5149\u5b66\u5206\u5272\u5264\u304c\u7121\u304f\u3066\u3082\u5149\u5b66\u5206\u5272\u3059\u308b\u3053\u3068\u304c\u3067\u304d\u308b(\u3053\u306e\u3088\u3046\u306a\u5149\u5b66\u5206\u5272\u6cd5\u3092\uff0c\u512a\u5148\u6676\u51fa\u6cd5\u3068\u3044\u3046)<sup> 5)<\/sup>\u3002 \u4e00\u65b9\u3067\uff0cAc-DL-aIle NH<sub>3<\/sub>\u306e\u7d50\u6676\u306b\u304a\u3044\u3066\u306f\uff0cAc-DL-aIle\u9670\u30a4\u30aa\u30f3\u3068\u30a2\u30f3\u30e2\u30cb\u30a6\u30e0\u30a4\u30aa\u30f3\u304c\u8907\u6570\u306e\u6c34\u7d20\u7d50\u5408\u306b\u3088\u3063\u3066\u3089\u305b\u3093\u3092\u5f62\u6210\u3059\u308b\u3088\u3046\u306b\u914d\u7f6e\u3055\u308c\u3066\u304a\u308a\uff0c\u4e00\u3064\u306e\u3089\u305b\u3093\u5185\u3067\u306f\u4e00\u65b9\u306e\u5149\u5b66\u7570\u6027\u4f53\u306e\u307f\u542b\u307e\u308c\u3066\u3044\u308b(\u56f3 5)\u3002\u30a2\u30f3\u30e2\u30cb\u30a6\u30e0\u30a4\u30aa\u30f3\u305d\u306e\u3082\u306e\u306f\u7b49\u4fa1\u306a\u56db\u3064\u306e N\uff0dH\u7d50\u5408\u3092\u6301\u3061\u30ad\u30e9\u30ea\u30c6\u30a3\u3092\u6301\u305f\u306a\u3044\u304c\uff0cAc-DL-aIle NH<sub>3<\/sub>\u306e\u7d50\u6676\u4e2d\u3067\u306f\u305d\u308c\u305e\u308c\u306e N\uff0dH\u7d50\u5408\u304cAc-DL-aIle\u9670\u30a4\u30aa\u30f3\u306e\u7570\u306a\u3063\u305f\u90e8\u4f4d\u306b\u6c34\u7d20\u7d50\u5408\u3057\u3066\u304a\u308a\uff0c\u3053\u306e\u3053\u3068\u306b\u3088\u308a\u3053\u306e\u7d50\u6676\u4e2d\u306b\u304a\u3044\u3066\u306f\u30a2\u30f3\u30e2\u30cb\u30a6\u30e0\u30a4\u30aa\u30f3\u306e\u7a92\u7d20\u539f\u5b50\u306b\u306f\u30ad\u30e9\u30ea\u30c6\u30a3\u304c\u3042\u308b\u3068\u307f\u306a\u3059\u3053\u3068\u304c\u3067\u304d\u308b\u3002\u3053\u306e\u3053\u3068\u306f\uff0c\u3053\u306e\u30a2\u30f3\u30e2\u30cb\u30a6\u30e0\u30a4\u30aa\u30f3\u3068 Ac-aIle\u9670\u30a4\u30aa\u30f3\u9593\u306e\u6c34\u7d20\u7d50\u5408\u306b\u3088\u308a\u751f\u3058\u308b\u30ad\u30e9\u30ea\u30c6\u30a3\u306b\u3088\u308a\uff0cAc-aIle\u9670\u30a4\u30aa\u30f3\u306e\u30ad\u30e9\u30ea\u30c6\u30a3\u3092\u8b58\u5225\u3057\u3066\u3044\u308b\u3068\u8003\u3048\u308b\u3053\u3068\u304c\u3067\u304d\u308b\u3002<\/p>\n\n\n\n<figure class=\"wp-block-image size-large\"><img loading=\"lazy\" decoding=\"async\" width=\"474\" height=\"547\" src=\"https:\/\/wps.itc.kansai-u.ac.jp\/cmr\/wp-content\/uploads\/sites\/189\/2020\/08\/\u30b9\u30e9\u30a4\u30c95-1.jpg\" alt=\"\" class=\"wp-image-66\" srcset=\"https:\/\/wps.itc.kansai-u.ac.jp\/cmr\/wp-content\/uploads\/sites\/189\/2020\/08\/\u30b9\u30e9\u30a4\u30c95-1.jpg 474w, https:\/\/wps.itc.kansai-u.ac.jp\/cmr\/wp-content\/uploads\/sites\/189\/2020\/08\/\u30b9\u30e9\u30a4\u30c95-1-260x300.jpg 260w\" sizes=\"auto, (max-width: 474px) 100vw, 474px\" \/><\/figure>\n\n\n\n<p>\u3000\u7acb\u4f53\u9078\u629e\u306b\u304a\u3051\u308b\u6c34\u7d20\u7d50\u5408\u306e\u91cd\u8981\u6027\u306f\uff0c\u91d1\u5c5e\u932f\u4f53\u3092\u5229\u7528\u3057\u305f\u30a2\u30df\u30ce\u9178\u8a98\u5c0e\u4f53\u306e\u5149\u5b66\u5206\u5272\u3067\u3082\u898b\u51fa\u3055\u308c\u3066\u3044\u308b<sup>6)<\/sup>\u3002(<em>R<\/em>)-<em>N<\/em>-(2-\u30d4\u30ea\u30b8\u30eb\u30e1\u30c1\u30eb)\u30d4\u30da\u30b3\u30ea\u30f3\u9178(pmpi)\u9285(II)\u932f\u4f53\u3092\u7528\u3044\u3066 (<em>RS<\/em>)-<em>N<\/em>-(<em>t<\/em>-\u30d6\u30c8\u30ad\u30b7\u30ab\u30eb\u30dc\u30cb\u30eb)\u30ed\u30a4\u30b7\u30f3 (BocLeu)\u3092\u5149\u5b66\u5206\u5272\u3057\u305f\u3068\u3053\u308d\uff0c\u518d\u7d50\u6676\u6eb6\u5a92\u306b\u6c34\uff0d\u30a2\u30bb\u30c8\u30cb\u30c8\u30ea\u30eb\u6df7\u5408\u6eb6\u5a92\u3092\u7528\u3044\u305f\u6642\u306f (<em>R<\/em>)-BocLeu\u932f\u4f53\u304c\uff0c\u30a2\u30bb\u30c8\u30f3\u3092\u7528\u3044\u305f\u6642\u306b\u306f (<em>S<\/em>)-BocLeu\u932f\u4f53\u304c\u7d50\u6676\u3068\u3057\u3066\u5f97\u3089\u308c\u305f\u3002\u4e21\u932f\u4f53\u306e\u6eb6\u5a92\u306b\u3088\u308b\u6eb6\u89e3\u5ea6\u306e\u9055\u3044\u306f\uff0c\u7d50\u6676\u4e2d\u306b\u304a\u3051\u308b\u6c34\u7d20\u7d50\u5408\u30cd\u30c3\u30c8\u30ef\u30fc\u30af\u306e\u9055\u3044\u306b\u8d77\u56e0\u3057\u3066\u3044\u308b\u3002(<em>R<\/em>)-BocLeu\u932f\u4f53(\u56f3 6a)\u306e\u7d50\u6676\u5316\u306b\u306f\u914d\u4f4d\u6c34\u304a\u3088\u3073\u7d50\u6676\u6c34\u304c\u5fc5\u8981\u3067\u3042\u308a\uff0c\u6c34\u3092\u542b\u307e\u306a\u3044\u6eb6\u5a92(\u30a2\u30bb\u30c8\u30f3\u7b49)\u4e2d\u3067\u306f\u7d50\u6676\u3092\u5f62\u6210\u3057\u306a\u3044\u3068\u8003\u3048\u3089\u308c\u308b\u304c\uff0c(<em>S<\/em>)-BocLeu\u932f\u4f53(\u56f3 6b)\u306f\u7d50\u6676\u751f\u6210\u306b\u6c34\u3092\u5fc5\u8981\u3068\u305b\u305a\uff0c\u914d\u4f4d\u5b50\u9593\u306e\u6c34\u7d20\u7d50\u5408\u3068\u9285(II)\u3078\u306e\u8ef8\u914d\u4f4d\u306b\u3088\u3063\u3066\u751f\u3058\u305f\u4e8c\u91cf\u4f53\u304c\u7a4d\u5c64\u3059\u308b\u3053\u3068\u306b\u3088\u308a\u7d50\u6676\u5316\u3057\u3066\u3044\u308b\u3002\u305d\u308c\u3068\u306f\u9006\u306b\u6c34\u3092\u542b\u3080\u6eb6\u5a92\u4e2d\u3067\u306f\uff0c(<em>R<\/em>)-BocLeu\u932f\u4f53\u3067\u306f\u914d\u4f4d\u6c34\u304a\u3088\u3073\u7d50\u6676\u6c34\u306e\u6c34\u7d20\u7d50\u5408\u30cd\u30c3\u30c8\u30ef\u30fc\u30af\u306b\u3088\u308a\u7d50\u6676\u5316\u304c\u4fc3\u9032\u3055\u308c\uff0c(<em>S<\/em>)-BocLeu\u932f\u4f53\u3067\u306f\uff0c\u4e8c\u91cf\u4f53\u3092\u5f62\u6210\u3059\u308b\u9285(II)\u30a4\u30aa\u30f3\u306e\u8ef8\u4f4d\u3078\u306e BocLeu\u306e\u914d\u4f4d\u3092\u6eb6\u5a92\u4e2d\u306e\u6c34\u304c\u963b\u5bb3\u3059\u308b\u305f\u3081\u306b\u7d50\u6676\u5316\u3057\u306b\u304f\u3044\u3068\u8003\u3048\u3089\u308c\u308b\u3002<\/p>\n\n\n\n<figure class=\"wp-block-image size-large\"><img loading=\"lazy\" decoding=\"async\" width=\"815\" height=\"411\" src=\"https:\/\/wps.itc.kansai-u.ac.jp\/cmr\/wp-content\/uploads\/sites\/189\/2020\/08\/\u30b9\u30e9\u30a4\u30c96-1.jpg\" alt=\"\" class=\"wp-image-67\" srcset=\"https:\/\/wps.itc.kansai-u.ac.jp\/cmr\/wp-content\/uploads\/sites\/189\/2020\/08\/\u30b9\u30e9\u30a4\u30c96-1.jpg 815w, https:\/\/wps.itc.kansai-u.ac.jp\/cmr\/wp-content\/uploads\/sites\/189\/2020\/08\/\u30b9\u30e9\u30a4\u30c96-1-300x151.jpg 300w, https:\/\/wps.itc.kansai-u.ac.jp\/cmr\/wp-content\/uploads\/sites\/189\/2020\/08\/\u30b9\u30e9\u30a4\u30c96-1-768x387.jpg 768w\" sizes=\"auto, (max-width: 815px) 100vw, 815px\" \/><\/figure>\n\n\n\n<p>4. \u82b3\u9999\u74b0(\u03c0-\u03c0)\u76f8\u4e92\u4f5c\u7528<\/p>\n\n\n\n<p>\u3000\u30d9\u30f3\u30bc\u30f3\u74b0\u306a\u3069\u306e\u82b3\u9999\u74b0\u306f\uff0c\u9175\u7d20\u306e\u8a8d\u8b58\u90e8\u4f4d\u3084\u8d85\u5206\u5b50\u306e\u5f62\u6210\u306a\u3069\u3067\u304a\u4e92\u3044\u304c\u63a5\u8fd1\u3057\u3066\u3044\u308b\u69d8\u5b50\u304c\u3088\u304f\u898b\u3089\u308c\uff0c\u305d\u308c\u3089\u306f\u7dcf\u79f0\u3057\u3066\u82b3\u9999\u74b0(\u03c0-\u03c0)\u76f8\u4e92\u4f5c\u7528\u3068\u547c\u3070\u308c\u308b\u3002\u82b3\u9999\u74b0\u306f\uff0c\u305d\u306e\u5bfe\u79f0\u6027\u306e\u9ad8\u3055\u3084\u69cb\u6210\u3059\u308b\u6c34\u7d20\u304a\u3088\u3073\u70ad\u7d20\u539f\u5b50\u306e\u96fb\u6c17\u9670\u6027\u5ea6\u304c\u305d\u308c\u307b\u3069\u5909\u308f\u3089\u306a\u3044\u3053\u3068\u306a\u3069\u304b\u3089\u6975\u6027\u304c\u5c0f\u3055\u304f\uff0c\u3057\u305f\u304c\u3063\u3066\u82b3\u9999\u74b0\u76f8\u4e92\u4f5c\u7528\u306f\u305d\u306e\u82b3\u9999\u74b0\u3092\u56f2\u3093\u3067\u3044\u308b\u6eb6\u5a92\u306a\u3069\u306e\u6c34\u7d20\u7d50\u5408\u306b\u8d77\u56e0\u3059\u308b\u758e\u6c34\u6027\u76f8\u4e92\u4f5c\u7528\u306e\u4e00\u7a2e\u3068\u8003\u3048\u3089\u308c\u3066\u304d\u305f\u3002\u3057\u304b\u3057\uff0c\u76f8\u4e92\u4f5c\u7528\u306e\u5f37\u5ea6\u304c\u7f6e\u63db\u57fa\u306e\u96fb\u5b50\u7684\u306a\u5f71\u97ff\u3092\u53d7\u3051\u308b\u3053\u3068\u304b\u3089<sup>7)<\/sup>\uff0c\u82b3\u9999\u74b0\u306e\u96fb\u5b50\u72b6\u614b\u304c\u82b3\u9999\u74b0\u76f8\u4e92\u4f5c\u7528\u306b\u5f71\u97ff\u3092\u4e0e\u3048\u308b\u3082\u306e\u3068\u8003\u3048\u3089\u308c\u308b\u3002\u3053\u306e\u3053\u3068\u306f\uff0c\u91d1\u5c5e\u932f\u4f53\u3092\u7528\u3044\u305f\u7cfb\u306b\u304a\u3044\u3066\u3082\u660e\u3089\u304b\u306b\u3055\u308c\u3066\u304a\u308a(\u56f3 7)<sup>8)<\/sup>\uff0c\u307e\u305f\u767d\u91d1(\u2161)\uff0d\u82b3\u9999\u65cf\u30a4\u30df\u30f3\u932f\u4f53\u3068\u82b3\u9999\u74b0\u3068\u306e\u76f8\u4e92\u4f5c\u7528\u306f\uff0c\u30a8\u30f3\u30bf\u30eb\u30d4\u30fc\u7684\u306b\u5b89\u5b9a\u5316\u3057\u3066\u3044\u308b\u3053\u3068\u304c\u793a\u3055\u308c\u3066\u3044\u308b<sup>9)<\/sup>\u3002\u3055\u3089\u306b\u306f\uff0c\u03c0-\u03c0\u76f8\u4e92\u4f5c\u7528\u306b\u3088\u308a\u82b3\u9999\u74b0\u4e0a\u306e\u6709\u6a5f\u30e9\u30b8\u30ab\u30eb\u304c\u5b89\u5b9a\u5316\u3055\u308c\u308b\u4e8b\u4f8b\u304c\u898b\u3064\u304b\u3063\u3066\u304a\u308a<sup>10)<\/sup>\uff0c\u7269\u8cea\u306e\u53cd\u5fdc\u6027\u306e\u5236\u5fa1\u3078\u306e\u03c0-\u03c0\u76f8\u4e92\u4f5c\u7528\u306e\u5fdc\u7528\u304c\u671f\u5f85\u3055\u308c\u308b\u3002<\/p>\n\n\n\n<figure class=\"wp-block-image size-large\"><img loading=\"lazy\" decoding=\"async\" width=\"831\" height=\"635\" src=\"https:\/\/wps.itc.kansai-u.ac.jp\/cmr\/wp-content\/uploads\/sites\/189\/2020\/08\/\u30b9\u30e9\u30a4\u30c97-1.jpg\" alt=\"\" class=\"wp-image-68\" srcset=\"https:\/\/wps.itc.kansai-u.ac.jp\/cmr\/wp-content\/uploads\/sites\/189\/2020\/08\/\u30b9\u30e9\u30a4\u30c97-1.jpg 831w, https:\/\/wps.itc.kansai-u.ac.jp\/cmr\/wp-content\/uploads\/sites\/189\/2020\/08\/\u30b9\u30e9\u30a4\u30c97-1-300x229.jpg 300w, https:\/\/wps.itc.kansai-u.ac.jp\/cmr\/wp-content\/uploads\/sites\/189\/2020\/08\/\u30b9\u30e9\u30a4\u30c97-1-768x587.jpg 768w\" sizes=\"auto, (max-width: 831px) 100vw, 831px\" \/><\/figure>\n\n\n\n<p>5.\n\u307e\u3068\u3081<\/p>\n\n\n\n<p>\u3000\u975e\u5171\u6709\u7d50\u5408\u6027\u76f8\u4e92\u4f5c\u7528\u304b\u3089\uff0c\u5bfe\u7167\u7684\u306a\u6c34\u7d20\u7d50\u5408\u3068\u82b3\u9999\u74b0\u76f8\u4e92\u4f5c\u7528\u306b\u3064\u3044\u3066\u7d39\u4ecb\u3057\u305f\u3002\u6c34\u7d20\u7d50\u5408\u306f\u305d\u306e\u76f8\u4e92\u4f5c\u7528\u539f\u7406\u306f\u3053\u308c\u307e\u3067\u306b\u3088\u304f\u7814\u7a76\u3055\u308c\u3066\u304a\u308a\uff0c\u4eca\u5f8c\u306f\u305d\u306e\u5fdc\u7528\u9762\u304c\u5927\u304d\u304f\u53d6\u308a\u4e0a\u3052\u3089\u308c\u3066\u304f\u308b\u3082\u306e\u3068\u601d\u308f\u308c\u308b\u3002\u305d\u308c\u306b\u5bfe\u3057\u3066\u03c0-\u03c0\u76f8\u4e92\u4f5c\u7528\u306f\uff0c\u305d\u306e\u76f8\u4e92\u4f5c\u7528\u539f\u7406\u304c\u3088\u304f\u308f\u304b\u3063\u3066\u3044\u306a\u3044\u3002\u4eca\u5f8c\uff0c\u305d\u306e\u539f\u7406\u304c\u660e\u3089\u304b\u306b\u306a\u308b\u306b\u3064\u308c\uff0c\u5206\u5b50\u8a8d\u8b58\u5834\u3042\u308b\u3044\u306f\u53cd\u5fdc\u306e\u5236\u5fa1\u306b\u5fdc\u7528\u3055\u308c\u308b\u3082\u306e\u3068\u671f\u5f85\u3055\u308c\u308b\u3002<\/p>\n\n\n\n<p>(\u95a2\u897f\u5927\u5b66\u7406\u5de5\u5b66\u4f1a\u8a8c\u300c\u7406\u5de5\u5b66\u3068\u6280\u8853\u300d\u300025\u5dfb\u300025\uff5e28\u30da\u30fc\u30b8\u3000(2018\u5e74)\u3000\u3088\u308a\u4e00\u90e8\u6539\u5909)<\/p>\n\n\n\n<p>\u53c2\u8003\u6587\u732e<\/p>\n\n\n\n<p>1) J. F. Stoddart, <em>Angew. Chem. Int. Ed.<\/em>, <strong>2017<\/strong>, <em>56<\/em>, 11094\u3068\u305d\u306e\u5f15\u7528\u6587\u732e.<\/p>\n\n\n\n<p>2) a) F. A. Quiocho, W. N. Lipscomb,\n<em>Adv. Protein Chem.<\/em>, <strong>1971<\/strong>, <em>25<\/em>, 1-78. b) J. H. Cho, D. H. Kim, S. J. Chung, N.-C. Ha, B.-H. Oh,\nK. Y. Choi, <em>Bioorg. Med. Chem.<\/em>, <strong>2002<\/strong>, <em>10<\/em>, 2015-2022.<\/p>\n\n\n\n<p>3) \u4f8b\u3048\u3070 S. T. Rao, F. Shaffie, C. Yu, K. A.\nSatyshur, B. J. Stockman, J. L. Markley, M. Sundarlingam, <em>Protein Sci.<\/em>, <strong>1992<\/strong>, <em>1<\/em>, 1413-1427.<\/p>\n\n\n\n<p>4) T. Yajima, M. Kitano, T.\nShiraiwa, \u672a\u767a\u8868\u30c7\u30fc\u30bf.<\/p>\n\n\n\n<p>5) T. Yajima, M. Kimura, Y. Hori,\nT. Shiraiwa, <em>Acta Crystallogr.<\/em>, <strong>2016<\/strong>, <em>B72<\/em>, 650-657.<\/p>\n\n\n\n<p>6) T. Yajima, T. Fukushima, A.\nYamada, T. Shiraiwa, <em>Inorg. Chim. Acta<\/em>,\n<strong>2017<\/strong>, <em>466<\/em>, 451-455.<\/p>\n\n\n\n<p>7) E. A. Meyer, R. K. Castellano,\nF. Diederrich, <em>Angew. Chem. Int. Ed.<\/em>,\n<strong>2003<\/strong>, <em>42<\/em>, 1210-1250\u3068\u305d\u306e\u5f15\u7528\u6587\u732e.<\/p>\n\n\n\n<p>8) T. Yajima, R. Takamido, Y.\nShimazaki, A. Odani, Y. Nakabayashi, O. Yamauchi, <em>Dalton Trans.<\/em>, <strong>2007<\/strong>,\n299-307.<\/p>\n\n\n\n<p>9) T. Yajima, G. Maccarrone, M. Takani,\nA. Contino, G. Arena, R. Takamido, M. Hanaki, Y. Funahashi, A. Odani, O.\nYamauchi, <em>Chem. Eur. J.<\/em>, <strong>2003<\/strong>, <em>9<\/em>, 3341-3352.<\/p>\n\n\n\n<p>10) H. Oshita, H. Abe, F. Tani, S. Mori, T. Yajima, Y. Shimazaki, <em>Chem. Eur. J.<\/em>, <strong>2019<\/strong>, <em>25<\/em>, 7649-7658. <\/p>\n","protected":false},"excerpt":{"rendered":"<p>1. \u306f\u3058\u3081\u306b \u3000\u751f\u547d\u6d3b\u52d5\u306b\u304a\u3051\u308b\u5316\u5b66\u53cd\u5fdc\u306e\u591a\u304f\u306b\u306f\u9175\u7d20\u304c\u95a2\u4e0e\u3057\u3066\u304a\u308a\uff0c\u7279\u5b9a\u306e\u7269\u8cea(\u57fa\u8cea)\u3092\u89e6\u5a92\u7684\u306b\u5909\u63db\u3057\u3066\u3044\u308b\u3002\u3053\u306e\u9175\u7d20\u53cd\u5fdc\u3092\u52b9\u7387\u3088\u304f\u884c\u3046\u306b\u306f\uff0c\u591a\u304f\u306e\u7269\u8cea\u306e\u4e2d\u304b\u3089\u5fc5\u8981\u3068\u3055\u308c\u308b\u57fa\u8cea\u3092\u9078\u5225\u3059\u308b\u5fc5\u8981\u304c\u3042\u308a\uff0c\u5206\u5b50\u306e\u5f62\u3092\u7279\u5b9a\u3057\u3066 &hellip; <a href=\"https:\/\/wps.itc.kansai-u.ac.jp\/cmr\/background\/\" class=\"more-link\">\u7d9a\u304d\u3092\u8aad\u3080 <span class=\"screen-reader-text\">\u7814\u7a76\u80cc\u666f<\/span> <span class=\"meta-nav\">&rarr;<\/span><\/a><\/p>\n","protected":false},"author":190,"featured_media":0,"parent":0,"menu_order":0,"comment_status":"closed","ping_status":"closed","template":"page-templates\/full-width.php","meta":{"_monsterinsights_skip_tracking":false,"_monsterinsights_sitenote_active":false,"_monsterinsights_sitenote_note":"","_monsterinsights_sitenote_category":0,"footnotes":""},"class_list":["post-49","page","type-page","status-publish","hentry"],"_links":{"self":[{"href":"https:\/\/wps.itc.kansai-u.ac.jp\/cmr\/wp-json\/wp\/v2\/pages\/49","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/wps.itc.kansai-u.ac.jp\/cmr\/wp-json\/wp\/v2\/pages"}],"about":[{"href":"https:\/\/wps.itc.kansai-u.ac.jp\/cmr\/wp-json\/wp\/v2\/types\/page"}],"author":[{"embeddable":true,"href":"https:\/\/wps.itc.kansai-u.ac.jp\/cmr\/wp-json\/wp\/v2\/users\/190"}],"replies":[{"embeddable":true,"href":"https:\/\/wps.itc.kansai-u.ac.jp\/cmr\/wp-json\/wp\/v2\/comments?post=49"}],"version-history":[{"count":8,"href":"https:\/\/wps.itc.kansai-u.ac.jp\/cmr\/wp-json\/wp\/v2\/pages\/49\/revisions"}],"predecessor-version":[{"id":138,"href":"https:\/\/wps.itc.kansai-u.ac.jp\/cmr\/wp-json\/wp\/v2\/pages\/49\/revisions\/138"}],"wp:attachment":[{"href":"https:\/\/wps.itc.kansai-u.ac.jp\/cmr\/wp-json\/wp\/v2\/media?parent=49"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}